The last globally stable extended alkane.

نویسندگان

  • Nils O B Lüttschwager
  • Tobias N Wassermann
  • Ricardo A Mata
  • Martin A Suhm
چکیده

Mother of all folding: cold isolated linear alkanes C(n)H(2n+2) prefer an extended all-trans conformation before cohesive forces between the chain ends induce a folded hairpin structure for longer chains. It is shown by Raman spectroscopy at 100-150 K that the folded structure becomes more stable beyond n(C) = 17 or 18 carbon atoms. High-level quantum-chemical calculations yield n(C) = 17 ± 1 as the critical chain length.

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عنوان ژورنال:
  • Angewandte Chemie

دوره 52 1  شماره 

صفحات  -

تاریخ انتشار 2013